Migrating Group Strategy for Remote Functionalization of Seven-Membered Rings

Wenlai, HanTaehwan, HwangChristina, LianSimon, KolbMina, Yamane, Vignesh Palani, Alison E. Wendlandt*

DOI: 10.1021/jacs.5c10470

Strain-inducing positional alkene isomerization.

Palani, V.; Wendlandt, A. E

DOI: 10.1021/jacs.3c06935

Stereochemical editing logic powered by the epimerization of unactivated tertiary stereocenters.

Zhang, Y.-A.*; Palani, V.*; Seim, A. E.; Wang, Y. Wang, K. J.; Wendlandt, A. E.

DOI: 10.1126/science.add6852

A stable alternative to an explosive synthetic reaction.

Palani, V.; Wendlandt, A. E.

DOI: 10.1021/jacs.3c06935

Catalytic, contra-thermodynamic positional alkene isomerization.

Occhialini, G.; Palani, V.; Wendlandt, A. E.

DOI: 10.1021/jacs.1c12043

Site-selective cross-coupling of polyhalogenated arenes and heteroarenes with identical halogen groups.

Palani, V.*; Perea, M. A.*; Sarpong, R.

DOI: 10.1021/acs.chemrev.1c00513

A pyrone remodeling strategy to access diverse heterocycles: application to the synthesis of fascaplysin natural products

Palani, V.; Perea, M. A.; Gardner, K. E.; Sarpong, R.

DOI: 10.1039/d0sc06317g

A Unified Strategy for the Enantiospecific Total Synthesis of Delavatine A and Formal Synthesis of Incarviaton A.

Palani, V.; Hugelshofer, C. L.; Sarpong, R.

DOI: 10.1021/jacs.9b07693

A Short Synthesis of Delavatine A Unveils New Insights into Site-Selective Cross-Coupling of 3,5-Dibromo-2-pyrone.

Palani, V.; Hugelshofer, C. L.; Kevlishvili, I.; Liu, P.; Sarpong, R.

DOI: 10.1021/jacs.8b13012

Calyciphylline B-type Alkaloids: Evolution of a Synthetic Strategy to (–)-Daphlongamine H.

Hugelshofer, C. L.; Palani, V.; Sarpong, R.

DOI: 10.1021/acs.joc.9b02223

Oxazaborinines from Vinylogous N-Allylic Amides: Reactivities of Underexplored Heterocyclic Building Blocks.

Hugelshofer, C. L.; Palani, V.; Sarpong, R.

DOI: 10.1021/acs.orglett.8b00859

Reactions of Diaziridines with Benzynes Give N-Arylhydrazones.

Arora, S.; Palani, V.; Hoye, T. R.

DOI: 10.1021/acs.orglett.8b03439

Atypical Mode of [3+2]-Cycloaddition: Pseudo-1,3-dipole Behavior in Reactions of Electron-Deficient Thioamides with Benzynes.

Zhang, J.; Page, A. C. S.; Palani, V.; Chen, J.; Hoye, T.R

DOI: 10.1021/acs.orglett.8b02133

Reactions of Hexadehydro-Diels–Alder (HDDA)-Derived Benzynes with Thioamides: Synthesis of Dihydrobenzothiazino-Heterocyclics.

Palani, V.; Chen, J.; Hoye, T. R

DOI: 10.1021/acs.orglett.6b03199

Reactions of HDDA-Derived Benzynes with Sulfides: Mechanism, Modes, and Three-Component Reactions

Chen, J.; Palani, V.; Hoye, T. R.